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Mass Concrete with Reduced Heat of Hydration


Cement hydration is an exothermic reaction, which results in the release of substantial heat in mass concrete. ACI Committee 116 defines mass concrete as "Any volume of concrete with dimensions large enough to require that measures be taken to cope with the generation of heat from the hydration of the cement and attendant volume change to minimize cracking." Typical areas of application include dams, tunnel linings, and concrete piers as well as large size columns, beams, walls, and foundations, where thermal action, durability, and economics are of primary concern.

In large pours, differences between surface temperatures and inner concrete temperatures during the hydration process induce thermal stresses at the surface, which lead to thermal cracking. The ACI 207 manual of concrete practice provides useful guidance with regard to temperature rises in traditionally placed and consolidated mass concrete. The type, content in the mix design, and fineness of the cement as well as aggregate content and coefficient of thermal expansion, diffusivity and elasticity modulus, section surface area ratio, and placement ambient temperatures are all factors affecting temperature rise. Although temperature increases occur within 1 to 3 days after casting, it may take years for thick sections to cool down back to ambient temperatures, as the heat generated by the concrete inner body cannot easily dissipate.

ASTM C 186 – Standard Test Method for Heat of Hydration of Hydraulic Cement is used to ascertain whether the hydraulic cement under test meets the heat of hydration specification at any age. To reduce temperature rises, the hydration process should be slowed down by reducing cement content to the extent possible while selecting cement with low tricalcium silicate (C₃S) and tricalcium aluminate (C₃A) contents. The cement content and type used are essential elements contributing to limiting temperature rises.

Aggregates with low coefficients of thermal expansion can significantly enhance thermal resistance by reducing thermal stresses, in many instances by half. In the selection of aggregates for use in mass concrete, it is important to maximize large size coarse aggregates, with aggregate size restrictions arising from practical limitations due to the forms and reinforcing steels. Furthermore, it is important to combine aggregates of different sizes to produce a gradation approaching maximum density on compaction. The use of rounded-shape aggregates enhances concrete workability and thus allows for an optimization of the mix design. The coarse aggregates absorption rate (less than 3%), specific gravity (greater than 2.5) and percentages of deleterious materials are also important factors in designing mass concrete mixes.

The use of supplementary cementitious materials such as fly ash (with Class F preferred) and Ground Granulated Blast Furnace Slag (GGBFS) as replacements of cement, in ranges, which can be up to 60% to 75%, can significantly reduce the heat of hydration to the extent of 15 to 50%. Highly reactive materials such as silica fume and metakaolin are not recommended for use in mass concrete. In addition, it should be noted that most fly ashes when used as pozzolans improve the workability of concrete allowing 5 to 8 % water reduction.

To reduce the heat of hydration, water reducers and/or high range water reducers are used to minimize both cement and water contents. The consistency of mass concrete should be as stiff as possible albeit still workable enough for the mix to be adequately placed and compacted. As a matter of fact, such concrete can be designed to achieve 13 MPa to 25 MPa, which might be required for interior concrete of large gravity structures, using water-cement ratios of 0.35 to 0.50 and slump values as low as 40 to 50 mm. Mass concrete may have air contents in the range of 3 to 5% or even increased to 8% as a means of increasing workability while keeping the water-cement content low. In addition, in the field, it is preferable to ensure the stiff concrete can be handled even if such handing may require special equipment, rather than plan to add water to improve workability. It is best placed in successive layers of 10 to 15 cm thickness depending on the aggregates' maximum size and the ability of the vibrator used to yield satisfactory results. In addition to water reducers and air entrainers, set-controlling admixtures are often required to ensure the inner concrete layers remain plastic so that successive layers can be placed and vibrated before the underlying layers set.

To reduce placement temperatures, flushing aggregates with cold water or alternatively pouring them in mixing water with flaked/crushed ice can cool the core of the concrete. The injection of liquid nitrogen in the mixing water is an alternative pre-cooling method used to reduce the concrete temperature. In placement operations, the core of the concrete may be cooled, with cold water flowing in pipes embedded in the concrete, or the outer surface insulated to reduce temperature differentials between the center and surface. Expansion reinforcements are useful for minimizing cracks. It is important to note that when the pre-cooling method is used, lab concrete tests should be carried out at a lower temperature rather than ambient temperature due to the slower hydration of cement at lower temperatures.

Holderchem can assist contractors and engineers in the design of durable mass concrete incorporating water reducers, air-entrainers, set controlling admixtures, and supplementary cementitious materials.

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Holderchem R&D seeks to develop solutions to meet construction challenges by bringing to market innovative products and systems, which offer benefits across the complete life cycle of buildings and other constructions. The aim is to supply customers with high-performance products to help them achieve better productivity, lower overall costs, and achieve extended service life and functionality. Research also aims at developing the Holderchem range of Batimix products with a particular focus on polymer emulsions, polymer-inorganic interactions, and product applications.
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